Chemical structure and reactivity of coordination compounds / Laboratory of coordination chemistry of alkali and rare metals
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Description
Main areas of workDevelopment of methods for the synthesis, preparation, study of the physicochemical properties and structure of new derivatives of crown ethers, including azamacrocyclic (porphyrins, phthalocyanines) and their mono- and heteronuclear coordination compounds containing N, O, P-ligand environment.
Extraction separation of metals and their isotopes using crown compounds; the study of extraction systems based on crown compounds for the separation of radionuclides, as well as the separation of radioactive metals from ballast metals.
Studying the features of the supramolecular chemistry of heterotopic receptors based on crown compounds.
The most significant results
Methods have been developed for the directed synthesis of a wide range of coordination compounds based on tetrapyrrole ligands - analogues of natural substances that ensure the vital activity of the biological world.
The fundamentals of new functional materials (thin films, polymer composites, hybrid materials) based on macrocyclic compounds and supramolecular architectures, as the basis of multifunctional devices of the new generation, have been developed.
Physical and chemical bases of radioactive waste processing based on macrocyclic extractants and sorbents of the new generation have been created.
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